Jenkins Groups Publications
54. Unmasking the Electrochemical Stability of N-Heterocyclic Carbene Monolayers on Gold, Dominique, Nathaniel L.; Chandran, Aruna; Jensen, Isabel M.; Jenkins, David M.; Camden, Jon P. Chem. Eur. J. 2023. 30, e202303681
53. Seeking a Au–C stretch on gold nanoparticles with 13C-labeled N-heterocyclic carbenes, Jensen, Isabel M.; Chowdhury, Shayanta; Hu, Gaohe; Jensen, Lasse; Camden, Jon P.; Jenkins, David M. Chem. Commun. 2023, 59 14524-14527.
Cover art for the Dec. 21st issue of Chemical Communications!
52. Reactivity variance between stereoisomers of saturated N-heterocyclic carbenes on gold surfaces, Kaur, Gurkiran; Dominique, Nathaniel L.; Hu, Gaohe; Naloah, Phattananawe; Thimes, Rebekah L.; Strausser, Shelby L.; Jensen, Lasse; Camden, Jon P.; Jenkins, David M. Inorg. Chem. Front. 2023. 10, 6282-6293.
51. Di-triazole boat conformation leads to metal–organic nanotube while chair conformation leads to coordination polymer, Nalaoh, Phattananawee; Jenkins, David M. CrystEngCom. 2023, 25, 4929-4933.
50. Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation, Pellitero, Miguel Aller; Jensen, Isabel M.; Dominique, Nathaniel L. Ekowo, Lilian Chinenye; Camden, Jon P.; Jenkins, David M; Arroyo-Currás, Netzahualcóyotl. ACS Appl. Mater. Interfaces. 2023, 15, 35701-35709.
Featured in Advances in Engineering!
49. Using Surfaced Enhanced Raman Spectroscopy to Unravel the Wingtip-Dependent Orientation of N-Heterocyclic Carbenes on Gold Nanoparticles, Thimes, Rebekah L.; Santos, Alyssa V. B.; Chen, Ran; Kaur, Gurkiran; Jensen, Lasse; Jenkins, David M.; Camden, Jon P. J. Phys. Chem. Lett. 2023, 14, 4219-4224.
48. Giving Gold Wings: Ultrabright and Fragmentation Free Mass Spectrometry Reporters for Barcoding, Bioconjugation Monitoring, and Data Storage, Dominique, Nathaniel L.; Jensen, Isabel M.; Kaur, Gurkiran; Kotseos, Chandler Q.; Boggess, William C.; Jenkins, David M.; Camden, Jon P. Angew. Chem. Int. Ed. 2023, 62, e202219182.
Inside cover art for the May 15th, 2023 issue of Angewandte Chemie!
47. Statistical copolymer metal organic nanotubes, Barrett, Jacob; Rosenmann, Nathan D.; Gnanasekaran, Karthikeyan; Carroll, Xian B.; Gianneschi, Nathan C.; Jenkins, David M. Chem. Sci. 2023, 14, 1003-1009.
46. Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles, Kaur, Gurkiran; Thimes, Rebekah L.; Camden, Jon P.; Jenkins, David M. Chem. Comm. 2022, 58, 13188-13197.
Inside cover art for the December 11, 2022 issue of Chemical Communications!
45. Ad aurum: tunable transfer of N-heterocyclic carbene complexes to gold surfaces, Dominique, Nathaniel L.; Chen, Ran; Santos, Alyssa V. B.; Strausser, Shelby L.; Rauch, Theodore; Kotseos, Chandler Q.; Boggess, William C.; Jensen, Lasse; Jenkins, David M.; Camden, Jon P. Inorg. Chem. Front. 2022, 9, 6279-6287.
44. Toward asymmetric aziridination with an iron complex supported by a D2-symmetric tetra-NHC, Blatchford, Kevin M.; Mize, Carson J.; Roy, Sharani; Jenkins, David M. Dalton Trans. 2022, 51, 6153-6156.
43. Late Lanthanide Macrocyclic Tetra-NHC Complexes, Carroll, Xian B.; Errulat, Dylan; Murugesu, Muralee; Jenkins, David M. Inorg. Chem. 2022, 61, 1611-1619.
42. N-Heterocyclic Carbene Ligand Stability on Gold Nanoparticles in Biological Media, Sherman, Lindy M.; Finley, Matthew D.; Borsari, Rowan K.; Schuster-Little, Naviya; Strausser, Shelby L.; Whelan, Rebecca J.; Jenkins, David M.; Camden, Jon P. ACS Omega. 2022, 7, 1444-1451.
41. Probing N-Heterocyclic Carbene Surfaces with Laser Desorption Ionization Mass Spectrometry, Dominique, Nathaniel L.; Strausser, Shelby L.; Olsen, Jacob E.; Boggess, William C.; Jenkins, David M.; Camden, Jon P. Anal. Chem. 2021, 93, 13534–13538.
40. Synthesis of d10 N-Heterocyclic Carbene Complexes with a Perimidine Scaffold, Strausser, Shelby L.; Jenkins, David M. Organometallics. 2021, 40, 1706-1712.
39. Actinide Tetra-N-heterocyclic Carbene ‘Sandwiches,’ DeJesus, Joseph F.; Kerr, Ryan W. F.; Penchoff, Deborah A.; Carroll, Xian B.; Peterson, Charles C.; Arnold, Polly L.; Jenkins, David, M. Chem. Sci. 2021,12, 7882-7887.
38. Imidazolinium N-Heterocyclic Carbene Ligands for Enhanced Stability on Gold Surfaces, Sherman Lindy M.; Strausser, Shelby L.; Borsari, Rowan K.; Jenkins, David M.; Camden, Jon P. Langmuir. 2021, 37, 5864–5871.
37. In Situ Monitoring of the Seeding and Growth of Silver Metal-Organic Nanotubes by Liquid-Cell Transmission Electron Microscopy, Gnanasekaran, Karthikeyan.; Vailonis, Kristina M.; Jenkins, David M.; Gianneschi, Nathan C. ACS Nano. 2020, 14, 8735-8743.
36. Investigating the Copolymerization of Ligands into Metal-Organic Nanotubes Using Small-Angle Neutron Scattering: Implications for Nanostraws, Shrestha, Umesh M.; Vailonis, Kristina M.; Jenkins, David M.; Dadmun, Mark D. ACS Appl. Nano. Mater. 2020, 3, 5605-5611.
35. A Benchtop Method for Appending Protic Functional Groups to N-Heterocyclic Carbene Protected Gold Nanoparticles, DeJesus, Joseph F.; Sherman, Lindy M.; Yohannan, Darius J.; Becca, Jeffrey C.; Strausser, Shelby L.; Karger, Leonhard F. P.; Jensen, Lasse; Jenkins, David M.; Camden, Jon P. Angew. Chem. Int. Ed. 2020, 59, 7585-7590.
34. A Chiral Macrocyclic Tetra‐N‐heterocyclic Carbene Yields an “All Carbene” Iron Alkylidene Complex, DeJesus, Joseph F.; Jenkins, David M. Chem. Eur. J. 2020, 26, 1429-1435.
33. One Macrocyclic Ligand, Four Oxidation States: A 16-Atom Ringed Dianionic Tetra-NHC Macrocycle and Its Cr(II) through Cr(V) Complexes, Anneser, Markus R.; Powers, Xian B.; Peck, KatieAnn M.; Jensen, Isabel M.; Jenkins, David, M. Organometallics. 2019, 38, 3369-3376.
32. Elucidating the Growth of Metal-Organic Nanotubes Combining Isoreticular Synthesis with Liquid-Cell Transmission Electron Microscopy, Vailonis, Kristina M.; Gnanasekaran, Karthikeyan; Powers, Xian B.; Gianneschi, Nathan C.; Jenkins, David M. J. Am. Chem. Soc. 2019, 141, 10177-10182.
Featured in July 19, 2019 edition of Science
31. Elucidation of the Reaction Mechanism of C2+ N1 Aziridination from Tetracarbene Iron Catalysts, Isbill, Sara B.; Chandrachud, Preeti P.; Kern, Jesse L.; Jenkins, David M.; Roy, Sharani. ACS Catal. 2019, 9, 6223-6233.
30. Unprecedented Five‐Coordinate Iron(IV) Imides Generate Divergent Spin States Based on the Imide R‐Groups, Anneser, Markus R.; Elpitya, Gaya R.; Townsend, Jacob; Johnson, Elizabeth J.; Powers, Xian B.; DeJesus, Joseph D.; Vogiatzis, Konstantinos D.; Jenkins, David M. Angew. Chem. Int. Ed. 2019, 58, 8115-8118.
29. Toward a Porphyrin-Style NHC: A 16-Atom Ringed Dianionic Tetra-NHC Macrocycle and Its Fe(II) and Fe(III) Complexes, Anneser, Markus R.; Elpitya, Gaya R.; Powers, Xian B.; Jenkins, David M. Organometallics. 2019, 38, 981-987.
28. Using SERS to Understand the Binding of N-Heterocyclic Carbenes to Gold Surfaces, Trujillo, Michael J.; Strausser, Shelby L.; Becca, Jeffrey C.; DeJesus,Joseph F.; Jensen, Lasse; Jenkins, David M.; Camden, Jon P. J. Phys. Chem. Lett. 2018, 9, 6779-6785.
27. Structural Characteristics, Population Analysis, and Binding Energies of [An(NO3)]2+ (with An = Ac to Lr), Penchoff, Deborah A.; Peterson, Charles C.; Quint, Mark S.; Auxier II, John C.; Schweitzer, George K.; Jenkins, David M.; Harrison, Robert J.; Hall, Howard L. ACS Omega 2018, 3, 14127-14143.
26. Structural Analysis of the Complexation of Uranyl, Neptunyl, Plutonyl, and Americyl with Cyclic Imide Dioximes, Penchoff, Deborah A.; Peterson, Charles C.; Camden, Jon P.; Bradshaw, James A.; Auxier II, John D.; Schweitzer, George K.; Jenkins, David M.; Harrison, Robert J.; Hall, Howard L. ACS Omega 2018, 3, 13984-13993.
25. N-Heterocyclic Carbenes as a Robust Platform for Surface-Enhanced Raman Spectroscopy, DeJesus, Joseph F.; Trujillo, Michael, J.; Camden, Jon P.; Jenkins, David M. J. Am. Chem. Soc. 2018, 140, 1247-1250.
24. Catalytic aziridination with alcoholic substrates via a chromium tetracarbene catalyst, Keller, C. Luke; Kern, Jesse L.; Terry, Bradley D.; Roy, Sharani; Jenkins, David M., Chem Commun, 2018, 54, 1429-1432.
23. Transition Metal Aziridination Catalysis, Chandrachud, Preeti P.; Jenkins, David M, Encyclopedia of Inorganic and Bioinorganic Chemistry, 2017, 1–11.
22. A Chromium(II) Tetracarbene Complex Allows Unprecedented Oxidative Group Transfer, Elpitiya, Gaya R.; Malbrecht, Brian J.; Jenkins, David M., Inorg. Chem., 2017, 56, 14101-14110.
21. Surface-enhanced Raman Scattering of Uranyl in Aqueous Samples: Implications for Nuclear Forensics and Groundwater Testing, Trujillo, M. J.; Jenkins, D. M.; Bradshaw, J. A.; Camden, J. P. Anal. Methods, 2017, 9, 1575-1579.
20. Synthesis of Fully Aliphatic Aziridines with a Macrocyclic Tetracarbene Iron Catalyst, Chandrachud, Preeti P.; Bass, Heather M; Jenkins, David M. Organometallics, 2016, 35, 1652–1657.
Cover art for the June 13, 2016 edition of Organometallics
19. Insights into the Morphology and Kinetics of Growth of Silver Metal–Organic Nanotubes, Etampawala, Thusitha; Mull, Derek L.; Keum, Jong K.; Jenkins, David M.; Dadmun, Mark Cryst. Growth Des., 2016, 16, 1395–1403.
18. Isoreticular synthesis of 2D MOFs with rotating aryl rings, Hughes, Brianna C.; Murdock, Christopher R.; Jenkins, David M. Inorg. Chem. Front., 2015, 2, 1001-1005.
17. High valent FeIV chemistry in sustainable oxidation catalysis, Chandrachud, Preeti P.; Jenkins, David M. Tetrahedron Lett., 2015, 56, 2369-2376.
16. Probing the Role of an FeIV Tetrazene in Catalytic Aziridination, Cramer, S. Alan; Sanchez, Raul Hernandez; Brakhage, Desirae F.; Jenkins, David M. Chem Commun, 2014, 50, 13967-13970.
15. Isostructural Synthesis of Porous Metal-Organic Nanotubes, Murdock, Christopher R. Jenkins, David, M. J. Am. Chem. Soc., 2014, 136, 10983–10988.
14. The Synthesis and Spectroscopic Characterization of an Aromatic Uranium Amidoxime Complex, Bernstein, Karl J.; Do-Thanh, Chi-Linh; Penchoff, Deborah A.; Cramer, S. Alan; Murdock, Christopher R.; Lu, Zheng; Harrison, Robert J.; Camden, Jon P.; Jenkins, David M. Inorg. Chim. Acta, 2014, 421, 374-379.
13. Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals, Cramer, S. Alan; Sturgill, Forrest L.; Chandrachud, Preeti P.; Jenkins, David M. Dalton Trans., 2014, 43, 7687-7690.
12. Rotating Phenyl Rings as a Guest-Dependent Switch in Two-Dimensional Metal–Organic Frameworks, Murdock, Christopher R.; McNutt, Nicholas W.; Keffer, David J.; Jenkins, David M. J. Am. Chem. Soc., 2014, 136, 671-678.
11. The final unadorned tris(azolyl)borate: finishing what Trofimenko started in 1966. Hughes, Brianna C.; Lu, Zheng; Jenkins, David M. Chem. Commun.,2014, 50, 5273-5275.
10. Approaches for synthesizing breathing MOFs by exploiting dimensional rigidity. Murdock, Christopher R.; Hughes, Brianna C.; Lu, Zheng; Jenkins, David M. Coord. Chem. Rev. 2014, 258-259, 119-136.
9.Efficient CO2 Capture by a 3D Porous Polymer Derived from Tröger’s Base. Zhu, Xiang; Do-Thanh, Chi-Linh; Murdock, Christopher R.; Nelson, Kimberly M.; Tian, Chengcheng; Brown, Suree; Mahurin, Shannon M.; Jenkins, David M.; Hu, Jun; Zhao, Bin; Liu, Honglai; Dai, Sheng. ACS Macro. Lett. 2013, 2, 660-663.
8. Employing Dianionic Macrocyclic Tetracarbenes To Synthesize Neutral Divalent Metal Complexes. Bass, Heather M.; Cramer, S. Alan; McCullough, Alexander S.; Bernstein, Karl J.; Murdock, Christopher R.; Jenkins, David M. Organometallics 2013, 32, 2160–2167.
7. Effects of Solvation on the Framework of a Breathing Copper MOF Employing a Semirigid Linker. Murdock, Christopher R.; Lu, Zheng; Jenkins, David M. Inorg. Chem. 2013, 52, 2182-2187.
6. Exploiting a dimeric silver transmetallating reagent to synthesize macrocyclic tetracarbene complexes. Lu, Zheng; Cramer, S. Alan; Jenkins, David M. Chem. Sci. 2012, 3, 3081-3087.
5. Atom-Economical C2 + N1 Aziridination: Progress towards Catalytic Intermolecular Reactions Using Alkenes and Aryl Azides. Jenkins, David M. Synlett 2012, 23,1267-1270.
4. Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF. Murdock, Christopher R.; Lu, Zheng; Jenkins, David M. Dalton Trans. 2012, 41, 7839-7841.
3. Chloride binding by a polyimidazolium macrocycle detected via fluorescence, NMR, and X-ray crystallography. Do-Thanh, Chi-Linh; Khanal, Neelam; Lu, Zheng; Cramer, S. Alan; Jenkins, David M.; Best, Michael D. Tetrahedron 2012, 68, 1669-1673.
2. Synthesis of Aziridines from Alkenes and Aryl Azides with a Reusable Macrocyclic Tetracarbene Iron Catalyst. Cramer, S. Alan; Jenkins, David. M. J. Am. Chem. Soc. 2011, 133, 19342-19345.
1. 18-Atom-Ringed Macrocyclic Tetra-imidazoliums for Preparation of Monomeric Tetra-carbene Complexes. Bass, Heather M.; Cramer, S. Alan; Price, Julia L.; Jenkins, David M. Organometallics 2010, 3235-3238.
Previous Publications by Professor Jenkins
12. Slow Magnetic Relaxation and Charge-Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN)7]3−/4−. Zadrozny, Joseph M.; Freedman, Danna E.; Jenkins, David M.; Harris, T. David; Iavarone, Anthony T.; Mathonière, Corine; Clérac. Rodophle; Long, Jeffery R. Inorg. Chem. 2010, 49, 8886-8896.
11. High-Spin Ground States via Electron Delocalization in Mixed-Valence Imidazolate-Bridged Divanadium Complexes. Bechlars, Bettina; D’Alessandro, Deanna M.; Jenkins, David M.; Iavarone, Anthony T.; Glover, Starla D.; Kubiak, Clifford P.; Long; Jeffrey R. Nature Chemistry 2010, 2, 362-368.
10. Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo). Freedman, Danna E.; Jenkins, David M.; Long, Jeffrey R. Chem. Commun. 2009, 4829-4831.
9. A Redox Switchable Single-Molecule Magnet Incorporating [Re(CN)7]3-. Freedman, Danna E.; Jenkins, David M.; Long, Jeffrey R. J. Am. Chem. Soc. 2008, 130, 2884-2885.
8. Vibrational Spectroscopy and Analysis of Pseudo-tetrahedral Complexes with Metal Imido Bonds. Mehn, Mark P.; Brown, Steven D.; Jenkins, David M.; Peters, Jonas C.; Que, Lawrence, Jr. Inorg. Chem. 2006, 45, 7417-7427.
7. Spin-State Tuning at Pseudotetrahedral d7 Ions: Examining the Structural and Magnetic Phenomena of Four-Coordinate [BP3]CoII-X Systems. Jenkins, David M.; Peters, Jonas C. J. Am. Chem. Soc. 2005, 127, 7148-7165.
6. Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion. Jenkins, David M.; Peters, Jonas C. J. Am. Chem. Soc. 2003, 125, 11162-11163.
5. Synthesis of 1,2-bis(di-tert-butylphosphino)ethane (dtbpe) Complexes of Nickel: Radical Coupling and Reduction Reactions Promoted by the Nickel(I) Dimer [(dtbpe)NiCl]2. Mindiola, Daniel J.; Waterman, Rory; Jenkins, David M.; Hillhouse, Gregory L. Inorg. Chim. Acta 2003, 345, 299-308.
4. Elucidation of a Low Spin Cobalt(II) System in a Distorted Tetrahedral Geometry. Jenkins, David M.; Di Bilio, Angel J.; Allen, Matthew J.; Betley, Theodore A.; Peters, Jonas C. J. Am. Chem. Soc. 2002, 124, 15336-15350.
3. Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex. Jenkins, David M.; Betley, Theodore A.; Peters, Jonas C. J. Am. Chem. Soc. 2002, 124, 11238-11239.
2. Redox Induced Reversible Structural Transformations of Dimeric and Polymeric Phenanthroline-Based Copper Chelates. Bernhard, Stefan; Takada, Kazutake; Jenkins, David; Abruña, Héctor D. Inorg. Chem. 2002, 41, 765-772.
1. A Homoleptic Phosphine Adduct of Tl(I). Shapiro, Ian R.; Jenkins, David M.; Thomas, J. Christopher; Day, Michael W.; Peters, Jonas C. Chem. Commun. 2001, 2152-2153.